In situ XRD investigation of the evolution of alumina-supported cobalt catalysts under realistic conditions of Fischer-Tropsch synthesis.
نویسندگان
چکیده
The structure-activity relations in the alumina-supported cobalt catalysts are studied at the realistic conditions of Fischer-Tropsch synthesis using in situ time-resolved XRD and catalytic measurements. Cobalt sintering during the first 3-5 h of the reaction and cobalt carbidisation at a longer time on stream (>8 h) coincide with catalyst deactivation.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 5 شماره
صفحات -
تاریخ انتشار 2010